杜恣毅,男,博士,二级教授,博士生导师,江西省主要学科学术和技术带头人,中国化学会高级会员,江西省百千万人才工程人选。主持承担了多项国家级、省部级自然科学基金项目。在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nat. Commum.、Chem. Commum.、Inorg. Chem.、Chin. J. Chem.、J. Mater. Chem. C、Cryst. Growth Des.、Dalton Trans.、CryEngComm、New J. Chem.等国际知名化学期刊上以第一作者/通讯作者身份发表论文60余篇。获评2020年度江西省自然科学奖一等奖(排名1);2008年度福建省科学技术奖一等奖(排名3)。
【研究领域】
无机化学专业。主要研究方向为功能配位化学、超分子化学、有机-无机杂化材料。近期的研究重点是晶态分子固体的分子动力学及结构相变调控、分子基光电极化材料的合成及相关性质的研究。
【代表性研究论文】
(1)Crystalline supramolecular gyroscope with a water molecule as an ultrasmall polar rotator modulated by charge-assisted hydrogen bonds. Wang Li, Chun-Ting He, Ying Zeng, Cheng-Min Ji, Zi-Yi Du*, Wei-Xiong Zhang*, Xiao-Ming Chen. J. Am. Chem. Soc. 2017, 139, 8086-8089.
(2)Switchable guest molecular dynamics in a perovskite-like coordination polymer toward sensitive thermoresponsive dielectric materials. Zi-Yi Du, Ting-Ting Xu, Bo Huang, Yu-Jun Su, Wei Xue, Chun-Ting He, Wei-Xiong Zhang*, Xiao-Ming Chen. Angew. Chem. Int. Ed. 2015, 54, 914-918.
(3)Molecular dynamics, phase transition and frequency-tuned dielectric switch of an ionic co-crystal. Jing-Yan Liu, Shi-Yong Zhang, Ying Zeng, Xia Shu, Zi-Yi Du*, Chun-Ting He*, Wei-Xiong Zhang*, Xiao-Ming Chen. Angew. Chem. Int. Ed. 2018, 57, 8032-8036.
(4)Molecule-based nonlinear optical switch with highly tunable on-off temperature using a dual solid solution approach. Shi-Yong Zhang, Xia Shu, Ying Zeng, Qing-Yan Liu, Zi-Yi Du*, Chun-Ting He*, Wei-Xiong Zhang*, Xiao-Ming Chen. Nat. Commun. 2020, 11, 2752.
(5)Above-room-temperature ferroelastic phase transition in a perovskite-like compound through azido ligand: [N(CH3)4][Cd(N3)3]. Zi-Yi Du, Ying-Ping Zhao, Wei-Xiong Zhang*, Hao-Long Zhou, Chun-Ting He, Wei Xue, Bao-Ying Wang, Xiao-Ming Chen. Chem. Commun. 2014, 50, 1989-1991.
(6)Insight into the molecular dynamics of guest cation confined in deformable azido coordination frameworks. Zi-Yi Du*, Yu-Zhi Sun, Shao-Li Chen, Bo Huang, Yu-Jun Su, Ting-Ting Xu, Wei-Xiong Zhang*, Xiao-Ming Chen. Chem. Commun. 2015, 51, 15641-15644.
(7)Solid solutions of flexible host−guest supramolecules for tuning molecular motion and phase transition. Xun-Hui Zhou, Ying Zeng, Shao-Bin Tang, Zi-Ru Yu, Li-Ming Cao, Zi-Yi Du*, Chun-Ting He. Chem. Commun. 2021, 57, 7292-7295.
(8)A crystalline supramolecular rotor functioned by dual ultrasmall polar rotators. Wang Li, De-Xuan Liu, Wei-Yu Hu, Qing-Yan Liu, Zi-Yi Du*, Chun-Ting He, Wei-Xiong Zhang*, Xiao-Ming Chen. Chin. J. Chem. 2022, 40, 1917-1923.
(9)Rational design of 0D, 1D and 3D open frameworks based on tetranuclear lanthanide(III) sulfonate-phosphonate clusters. Zi-Yi Du, Hai-Bing Xu, Jiang-Gao Mao*. Inorg. Chem. 2006, 45, 9780-9788.
(10)Three novel zinc(II) sulfonate-phosphonates with tetranuclear or hexanuclear cluster units. Zi-Yi Du, Hai-Bing Xu, Jiang-Gao Mao*. Inorg. Chem. 2006, 45, 6424-6430.
(11)Novel manganese(II) sulfonate-phosphonates with dinuclear, tetranuclear and hexanuclear clusters. Zi-Yi Du, Andrew Prosvirin, Jiang-Gao Mao*. Inorg. Chem. 2007, 46, 9884-9894.
(12)Octanuclear aluminum(III) and iron(III) phosphonate cages encapsulating two NaI ions. Zi-Yi Du*, Yu-Hui Sun, Qing-Yan Liu*, Yong-Rong Xie, He-Rui Wen. Inorg. Chem. 2009, 48, 7015-7017.
(13)Plastic crystals with polar halochromate anion: Thermosensitive dielectrics based upon plastic transition and dipole rotation. Yu-Zhi Sun, Bo Huang, Wei-Jian Xu, Dong-Dong Zhou, Shao-Li Chen, Shi-Yong Zhang, Zi-Yi Du*, Yong-Rong Xie, Chun-Ting He*, Wei-Xiong Zhang*, Xiao-Ming Chen. Inorg. Chem. 2016, 55, 11418-11425.
(14)Matching of host-guest symmetry/orientation and molecular dynamics in two double perovskite-like azido coordination polymers. Ying Zeng, Rui-Kang Huang, Zi-Yi Du*, Chun-Ting He*, Wei-Xiong Zhang*, Xiao-Ming Chen. Inorg. Chem. 2017, 56, 9946-9953.
(15)Insights into the molecular dynamics of quasi-spherical (chloromethyl)triethylammonium confined in a weakly bound ionic cocrystal. Ci-Ci Sun, Wang Li, De-Xuan Liu, Zi-Yi Du*, Chun-Ting He, Wei-Xiong Zhang,* Xiao-Ming Chen. Inorg. Chem. 2022, 61, 7201-7206.
【教学与人才培养工作】
主要从事与无机化学相关的教学工作。指导的多名研究生获评研究生国家奖学金以及江西省优秀硕士论文。
【联系方式】
E-mail:dzychem@163.com